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synthesis and spectroscopic characterization of two tetrasubstituted cationic porphyrin derivatives合成和两个tetrasubstituted阳离子卟啉衍生物的光谱特性.pdf

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Molecules 2011, 16, 5807-5821; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Synthesis and Spectroscopic Characterization of Two Tetrasubstituted Cationic Porphyrin Derivatives Antonio E.H. Machado 1,*, Weverson R. Gomes 1, Diesley M.S. Araújo 1, Hércules S. Miglio 2, Leonardo T. Ueno 3, Rodrigo De Paula 4,5, José A.S. Cavaleiro 5 and Newton M. Barbosa Neto 6 1 Laboratório de Fotoquímica, Instituto de Química, Universidade Federal de Uberlândia, P.O. Box 593, CEP 38400-902 Uberlândia, Minas Gerais, Brazil 2 Centro de Ciências Agrárias, Universidade Federal do Espírito Santo, Alegre, Espírito Santo, Brazil; E-Mail: herculesmiglio@ 3 Faculdade de Ciências Integradas do Pontal, Universidade Federal de Uberlândia, Ituiutaba, Minas Gerais, Brazil; E-Mail: tsuyoshi@pontal.ufu.br 4 Centro de Formação de Professores, Universidade Federal do Recôncavo da Bahia, Amargosa, Bahia, Brazil; E-Mail: rodrigodepaula@.br 5 Departamento de Química,Universidade de Aveiro, Aveiro, Portugal; E-Mail: jcavaleiro@ua.pt 6 Instituto de Física, Universidade Federal de Uberlândia, P.O. Box 593; CEP 38400-902 Uberlândia, Minas Gerais, Brazil; E-Mail: newtonfisico@ * Author to whom correspondence should be addressed; E-Mail: aeduardo@ufu.br; Tel.: +55-34-3239-4428; Fax: +55-34-3239-4208. Received: 17 April 2011; in revised form: 6 July 2011 / Accepted: 7 July 2011 / Published: 8 July 2011 Abstract: An imidazolium tetrasubstituted cationic porphyrin derivative (the free base and its Zn(II) complex) with five-membered

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