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synthesis, properties characterization and applications of various organobismuth compounds各种organobismuth化合物的合成、性能表征和应用程序.pdf

发布：2017-09-10约17.41万字共40页下载文档

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Molecules 2011, 16, 4191-4230; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Review Synthesis, Properties Characterization and Applications of Various Organobismuth Compounds Jingfei Luan *, Lingyan Zhang and Zhitian Hu State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210093, China; E-Mails: zhanglingyanyaner@163.com (L.Z.), huzt123@126.com (Z.H.) * Author to whom correspondence should be addressed; E-Mail: jfluan@; Tel.: +86-135-8520-6718; Fax: +86-25-8370-7304. Received: 15 April 2011; in revised form: 9 May 2011 / Accepted: 12 May 2011 / Published: 20 May 2011 Abstract: Organobismuth chemistry was emphasized in this review article due to the low price, low toxicity and low radioactivity characteristics of bismuth. As an environmentally- friendly class of organometallic compounds, different types of organobismuth compounds have been used in organic synthesis, catalysis, materials, etc. The synthesis and property characterization of many organobismuth compounds had been summarized. This review article also presented a survey of various applications of organobismuth compounds in organic transformations, as reagents or catalysts. The reactivity, reaction pathways and mechanisms of reactions with organobismuths were discussed. Less common and limiting aspects of organobismuth compounds were also briefly mentioned. Keywords: organobismuth compounds; synt

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