synthesis and spectral evaluation of some unsymmetrical mesoporphyrinic complexes一些不对称合成和光谱评价mesoporphyrinic复合物.pdf
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Int. J. Mol. Sci. 2012, 13, 8112-8125; doi:10.3390/ijm
OPEN ACCESS
International Journal of
Molecular Sciences
ISSN 1422-0067
/journal/ijms
Article
Synthesis and Spectral Evaluation of Some Unsymmetrical
Mesoporphyrinic Complexes
Rica Boscencu 1,*, Anabela Sousa Oliveira 2,3, Diana P. Ferreira 2 and
Luís Filipe Vieira Ferreira 2
1 Faculty of Pharmacy, “Carol Davila” University of Medicine and Pharmacy, 6 Traian Vuia St.,
Bucharest 020956, Romania
2 Molecular Physical Chemistry Center, IN—Institute of Nanoscience and Nanotechnology,
Technical University of Lisbon, Av. Rovisco Pais, Lisbon 1049-001, Portugal;
E-Mails: asoliveira@estgp.pt (A.S.O.); diana.ferreira@ist.utl.pt (D.P.F.);
luisfilipevf@ist.utl.pt (L.F.V.F.)
3 School of Technology and Business, Polytechnic Institute of Portalegre, Lugar da Abadessa,
Apartado 148, Portalegre 7301-901, Portugal
* Author to whom correspondence should be addressed; E-Mail: rboscencu@;
Tel./Fax: +4021-3111152.
Received: 15 February 2012; in revised form: 13 June 2012 / Accepted: 21 June 2012 /
Published: 29 June 2012
Abstract: Synthesis and spectral evaluation of new zinc and copper unsymmetrical
mesoporphyrinic complexes are reported. Zn(II)-5-(4-acetoxy-3-methoxyphenyl)-10,15,20-
tris-(4-carboxymethylphenyl)porphyrin, Zn(II)-5-[(3,4-methylenedioxy)phenyl]-10,15,20-
tris-(4-carboxymethylphenyl)porphyrin, Cu(II)-5-(4-acetoxy-3-methoxyphenyl)-10,15,20-
tris-(4-carboxymethylphenyl)porphyrin and Cu(II)-5-
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