synthesis of new phosphorus-containing (co)polyesters using solid-liquid phase transfer catalysis and product characterization使用固液合成新的卤(co)聚酯相转移催化和产品描述.pdf

Molecules 2012, 17, 9090-9103; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Synthesis of New Phosphorus-Containing (Co)Polyesters Using Solid-Liquid Phase Transfer Catalysis and Product Characterization 1 2 1 1 Smaranda Iliescu , Maite-Gyl Augusti , Eugenia Fagadar-Cosma , Nicoleta Plesu , Gheorghe Fagadar-Cosma 3, Lavinia Macarie 1, Adriana Popa 1 and Gheorghe Ilia 1,* 1 Institute of Chemistry, Romanian Academy, 24 Mihai Viteazul Bvd., Timisoara 300-223, Romania; E-Mails: smail@.ro (S.I.); efagadar@ (E.F.-C.); plesu_nicole@ (N.P.); lavi_mac@ (L.M.); apopa_ro@ (A.P.) 2 Instituto Tecnológico de la Energía, Av. Juan de la Cierva, 24 Parque Tecnológico de Valencia, Paterna 46980 (Valencia), Spain; E-Mail: mayte.gil@ite.es 3 Polytechnic University of Timisoara T. Lalescu Street, No. 2, Timisoara 300-223, Romania; E-Mail: gfagadar@ * Author to whom correspondence should be addressed; E-Mail: ilia@.ro; gheilia@; Tel.: +40-025-649-1818; Fax: +40-025-649-1824. Received: 13 June 2012; in revised form: 12 July 2012 / Accepted: 24 July 2012 / Published: 31 July 2012 Abstract: This paper is directed towards the development of safe, and thermally stable solid polymer electrolytes. Linear phosphorus-containing (co)polyesters are described, including their synthesis, thermal analysis, conductivity, and non-flammability. Polycondensation of phenylphosphoni