[英语学习]化学专业英语前言翻译.pdf

3.Abstract

Reactionsbetweenhexanuclearmanganesepivalatewithlanthanidesalts(chloridesornitrates),inthe

presenceofpotassiumhydroxide,2-pyridylmethanolandsodiumazideleadstoformationofanewfamily

ofhexaheteronuclearmanganese–lanthanideclusters.

4.Abstract

Twonovelmetal–organicframeworksof[M(ptz)(N)(HO)](M=Zn(1),Cd(2))(ptz=

323422

5-(4-pyridyl)tetrazolate)havebeenpreparedhydro(solvo)thermallybyreactionsof4-cyanopyridineand

excessNaNinthepresenceofzincandcadmiumchloride,respectively.Theoverallstructuremotifof

3

complexes1and2showpillaredlayeredframeworksandfeatureanunprecedented3-nodalnetwork

with(3,5,6)-connectivity.Thelayerisofparticularinterestasitisconstructedbyμ1,1–N3−andμ1,1,3–N3−

bridgingmodes,simultaneously.Furthermore,thesolidfluorescentpropertiesandTGAwerestudied.

5.Abstract

II

StructuralcharacterizationofanewselfassembledcoordinationpolymerofCu,hexamine(hmt)and

benzoate(OBz),[Cu(OBz)(hmt)](1),revealsthatitisacubicnon-interpenetratingdiamondoidnetwork

48n

formedbythecoordinationoftheμ-hmtligandtoalinear[Cu(OBz)]spacer.Themagneticstudy

424

revealsthattheCu(II)ionsareantiferromagneticallycoupled(J=−323.5cm−1)throughthesyn–syn

carboxylatebridges.

6.Abstract

2+

SimplePETchemosensorsbasedonanthraceneshowaselectiveturn-onfluorescencesensingforCu.

Theflexiblereceptorisfavorableforturn-on