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Hydrothermal Synthesis and Crystal.pdf

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24 卷3 期 结 构 化 学 (JIEG OU HUAXUE ) Vol. 24. No.3 2005. 3 Chinese J. Struct. Chem. 291~294 Hydrothermal Synthesis and Crystal Structure of a Three-dimensional ① Compound {Mn(H O) (VO) (PO ) } 2 4 2 4 2 n WU Yanga JIANG Xiao-Yub ZHANG Quan-Zhengc CHEN Li-Juanc YU Ya-Qinc CHEN Shu-Meic HE Xiangc YANG Wen-Binc LU Can-Zhongc② a (College of Chemistry Materials Science, Fujian Normal University, Fuzhou 350007, China) b (Fujian University of Technology, Fuzhou, Fujian 350007, China) c (State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China) ABSTRACT The title compound, {Mn(H O) (VO) (PO ) } 1, was synthesized by the hydro- 2 4 2 4 2 n thermal reaction of Mn(OAc) , Na VO and H PO in aqueous solution and its crystal structure was 2 2 3 3 4 determined by X-ray single-crystal analysis. Crystallographic data for 1: H MnO P V , tetragonal 4 14 2 2
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