Microstructure thermostability of high nitrogen austenitic stainless steel.pdf
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Microstructure thermostability of high nitrogen
austenitic stainless steel1
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Zhizhong Yuan , Qixun Dai, Xiaonong Cheng, Kangmin Chen, Jing Wu
School of Materials Science and Engineering, Jiangsu University, Zhenjiang, Jiangsu
212013, PR China
Abstract: High nitrogen austenitic stainless steel, Fe24Mn18Cr3Ni0.62N, was
isothermal annealed from 750 to 900 for different time to investigate the
thermostability of its microstructures. Results show that precipitations were Cr2N and
firstly formed along the grain boundary. The time-temperature-precipitation diagram
was established, according to which the critical cooling rate of this material with less
than 0.1~0.5 vol. % of precipitated Cr2N was specified as 30 /min. The
microhardness of the matrix in samples annealed at different temperatures decreased
with the diffusion of nitrogen from the matrix to grain boundaries.
Key words: Austenitic stainless steels, Nitrogen, Thermostability, Nitride
1. Introduction
Basically, there are three categories of thermostability during the manufacture and
heat treatment of austenitic stainless steels (ASS): formation of δ ferrite at high
temperature; martensite transformation at cryogenic temperature; carbide, nitride and
other intermetallics precipitate under certain heating conditions. The third one is very
important for ASS with nitrogen content, which is very important for cryogenic
application and attracts great attention [1-5]. Nitrogen alloyed ASS are easy to
precipitated Cr N at temperatures ranging from 500 to 105, which will result in
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