synthesis, crystal structure, and kinetics of the thermal decomposition of the nickel(ii) complex of the schiff base 2-[(4 methylphenylimino)methyl]-6-methoxyphenol合成、晶体结构和动力学的热分解镍(ii)复杂的席夫碱2 -[(4 methylphenylimino)甲基]6-methoxyphenol.pdf

Molecules 2009, 14, 2582-2593; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Synthesis, Crystal Structure, and Kinetics of the Thermal Decomposition of the Nickel(II) Complex of the Schiff Base 2-[(4-Methylphenylimino)methyl]-6-methoxyphenol 1,2 1 1 1, Yan-Fang Wang , Jian-Feng Liu , Hui-Duo Xian and Guo-Liang Zhao * 1 Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, 321004, China 2 Ningbo Tian Yi College of Occupation and Technology, Ningbo, Zhejiang 315100, China; E-mails: yfw901@163.com (Y-F.W.); liujianfeng23@163.com (J-F.L.); hdxian@163.com (H-D.X.) * Author to whom correspondence should be addressed; E-mail: sky53@; Tel.: +86-579 Fax: +86-579 Received: 25 May 2009; in revised form: 29 June 2009 / Accepted: 13 July 2009 / Published: 15 July 2009 Abstract: A new dinuclear complex, [Ni (H O)L ]·5H O, consisting of chelating bidentate 2 2 4 2 and bridging tridentate coordinated 2-[(4-methylphenylimino)methyl]-6-methoxyphenol (HL) Schiff base ligands and water molecules has been synthesized using a traditional method. The structure of this complex was characterized by FTIR and UV/Vis spectroscopy and thermogravimetric analyses (TG-DTG) and furth