氮苯四甲酸锰(II)配合物的合成与晶体结构【毕业设计】.doc
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本科毕业设计
吡啶四甲酸锰(II)配合物的合成与晶体结构
Syntheses and structural characterization of Pyridine-2,3,5,6-tetracarboxylate Mn(II) complexe
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专业班级 化学
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吡啶四甲酸锰(Ⅱ)配合物的合成与晶体结构
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摘 要
【摘要】基于多羧酸锰配合物的合成探索与研究对于开发新型分子基磁性材料、光电功能材料以及新型催化材料等具有十分重要的意义,于此,人们对寻找更好的模型化合物进行生物功能模拟也具有重要的研究价值。本论文在对一定量文献报道的锰有机羧酸配合物的结构类型、性质研究以及它的合成方法进行了一个比较性的综述。同时,在本文的工作中对合成得到的Mn(II)配位聚合物进行了x-射线单晶衍射、红外光谱、热化学性质等的表征。
在乙醇/水混合溶剂中,Mn(II)离子、2,3,5,6-吡啶四甲酸(H4pdtc)与2,2’-联吡啶(bpy)自组装得到1例Mn(II)配位聚合物: [Mn(bpy)2(H2pdtc)]。该配合物为单斜晶系,P2(1)/n空间群,a = 7.771(1) (?), b = 26.417(5) (?), c = 12.938(3) (?), ???????????? (?), 以及Dcalc = 1.556 g/cm3, Z = 4.
【关键词】锰(II)配合物;晶体结构;金属有机配合物;2,3,5,6-吡啶四甲酸。
Syntheses and structural characterization of Pyridine-2,3,5,6-tetracarboxylate Mn(II) complexe Abstract
【ABSTRACT】The explorations and researches based on multi-carboxylic acid manganese complexes are of great value to develop new molecular base magnetic materials, photoelectric functional materials and new catalytic materials. Besides, it’s also has a great significance for people to look for better model compounds to do biological functional tests. This dissertation, conducted from a comparative perspective, summarizes a certain amount of papers and reports related to Manganese organic acid complexes’ structual types , character researches as well as it’s compounds methods . Meanwhile, work in this paper obtained on the synthesis of Mn (II) coordination polymers were x-ray diffraction, infrared spectroscopy, thermal and chemical properties such as the characterization.
In ethanol / water mixed solvents, when Mn (II), Pyridine-2,3,5,6-tetracarboxylate (H4pdtc) and 2,2 - bipyridine (bpy) assembled automatically, then a Mn (II) coordination polymer: [Mn (bpy) 2 (H2pdtc)] will come into being. The complex belongs to monoclinic, P2 (1) / n space group, a = 7.7
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