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1 states of matter Alevel考试化学课件.pptx

发布:2024-02-16约4.03千字共23页下载文档
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Chapter4

StatesofmatterWhatarethethreestatesofmatterDifferencesinpropertiesofsolids,liquidsandgases

Whatarethethreestatesofmatter?

solidliquidgas

DefiniteshapeDefinitevolumeParticlesmoveveryslowlyParticlesofsolidsaretightlypacked,vibratingaboutafixedposition.solid

ThearrangementofparticlesinasolidTherearemanytypesofsolid,whosepropertiesdependontheparticlesthattheycontain.Theparticlesinasolidareveryorderlyarrangement,butevenat0K,theatomsarenotcompletelystill,theyvibrateaboutthesameaverageposition.

Indefiniteshape,definitevolumeTaketheshapeofcontainerParticlesareclosetogether,butmobileParticlesmoveslowlyliquid

HowmuchorderisthereinaliquidTheparticlesinaliquidgrouptogether,andjustthetendencyproducessomeorderintheirarrangement.However,theorderisoverarelativelyshortrange,perhapsoveradistanceof10-9m(about10moleculardiameters).Overgreaterdistances,thedegreeoforderdiminishes.Wecansummarise:inaliquidthereisshort-rangeorder,andlong-rangedisorder.

IndefiniteshapeIndefinitevolumeTaketheshapeandvolumeofcontainerParticlesarefarapartParticlesmovefastgas

HowdoweknowthatgasesaredisorderRobertBrownin1827observedthemovementofpollenonthesurfaceofwatertobecompletelyunpredictable,justlikeaverydrunkperson.Thereasonwhythegrainsbehaveinthiswayisthattheyarebeingbombardedbymoleculesintheliquid,whicharethemselvesmovinginarandomway.Around1908JeanPerrinmadeobservationsofBrownainmotioningases.ThiscouldbeexplainedalongthesamelinesasBrownianmotioninliquids.Theparticleswerebeingstruckbytherandomlymovinggasmolecules.

Thethreestatesofmatteraresolid,liquidandgas.Whetherasubstanceexistsasasolid,liquidorgasmainlydependsontwothings.1kineticenergy–whichincreasesasasubstanceisheated.

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