conversion of co2 via visible light promoted homogeneous redox catalysis通过可见光转换的二氧化碳促进了均匀氧化还原催化.pdf

Catalysts 2012, 2, 544-571; doi:10.3390/catal2040544 OPEN ACCESS catalysts ISSN 2073-4344 www.mdpi.cosm/journal/catalysts Review Conversion of CO via Visible Light Promoted Homogeneous 2 Redox Catalysis Richard Reithmeier, Christian Bruckmeier and Bernhard Rieger * Catalysis Research Centre, WACKER-Chair of Macromolecular Chemistry, TU-Munich, Lichtenbergstraße 4, 85748 Garching, Germany; E-Mails: richard.reithmeier@mytum.de (R.R.); christian.bruckmeier@mytum.de (C.B.) * Author to whom correspondence should be addressed; E-Mail: rieger@tum.de; Tel.: +49-89-289-13571; Fax: +49-89-289-13562. Received: 27 August 2012; in revised form: 26 October 2012 / Accepted: 13 November 2012 / Published: 27 November 2012 Abstract: This review gives an overview on the principles of light-promoted homogeneous redox catalysis in terms of applications in CO conversion. Various chromophores and the 2 advantages of different structures and metal centers as well as optimization strategies are discussed. All aspects of the reduction catalyst site are restricted to CO conversion. An 2 important focus of this review is the question of a replacement of the sacrificial donor which is found in most of the current publications. Furthermore, electronic parameters of supramolecular systems are reviewed with reference to the requisite of