固体超强酸催化剂及其在异丁烷丁烯烷基化中的应用研究进展.pdf

2006 10 Oct.2006 14 10 INDUSTRIAL CATALYSIS Vol. 14 No. 10 / 1 2 1 1 陈其凤, 王鼎聪 , 赵杉林, 李 萍 ( 1. , 113001; 2. , 113001) : 叙述了目前固体超强酸的研究现状及其研究重点和方向综述了现有的用于烷基化反应 的固体超强酸 化剂, 包括金属卤化物 化剂分子筛 化剂金属氧化物固体超强酸 化剂和杂 多酸 化剂对Aklylene 工艺AlkyClean 工艺Lurgi 工艺和 BA 工艺等目前世界上的主要烷基 化工艺以及国内工艺作了描述 : 固体超强酸; 化剂; 烷基化 + :TE624.4 8; TQ426. 95 :A :2006) Advances in solid superacid catalysts and their application in isobutane/ butylene alkylation 1 2 1 1 CH EN Qif eng , WA N G Di ngcong , ZHA O Shanl in , L I P ing ( 1. Liaoning U niversity of Petroleum and Technology, ushun 113001, Liaoning, China; 2. Sinopec ushun Research Institute of Petroleum Petrochemicals, ushun 113001, Liaoning, China) Abstract: Latest researches in solid superacid catalysts and the focus and trends in this aspect were out lined and existing solid superacid catalysts for alkylation were reviewed, including metal halides cata lysts, zeolite catalysts, metal oxide catalysts and heteropolyacid catalysts. Main processes, such as Alkylene, AlkyClean, Lurgi and BA processes were described. Key words: solid superacid; catalyst; alkylation + CLC number:TE624.4 8; TQ426.95 Document code: A Article ID:2006) , H2SO4 , , , 1 , , , , ( SAC) , , , , , , : : ( 2005~ 2006,05L227) : ( 1974- ) , , , ,