阳离子固体电解质的研究进展.pdf

第 38 卷第 2 期 唐山师范学院学报 2016 年 3 月 Vol.38 No.2 Journal of Tangshan Normal University Mar. 2016 化学与化工研究 阳离子固体电解质的研究进展 1 1 1,2 1 1,2 史 明 ，周会珠 ，戴 磊 ，李跃华 ，王 岭 （1. 华北理工大学 化学工程学院，河北 唐山 063009 ；2. 河北省环境光电催化材料重点实验室，河北 唐山 063009 ） 摘 要：近年来，固体电解质材料作为一种新型功能材料蓬勃发展并被广泛研究。论文主要就一价、二价、 三价和四价阳离子传导固体电解质的研究进行了综述，着重介绍了三价和四价两种高价阳离子固体电解质的研 究现状，简要介绍了固体电解质在电化学气体传感器方面的应用，总结了其在现阶段研究中遇到的问题，并对 未来的应用和发展前景进行了展望。 关键词：阳离子固体电解质；NASICON ；气体传感器 TB34 A 1009-9115(2016)02-0030-05 中图分类号： 文献标识码： 文章编号： DOI ：10.3969/j.issn.1009-9115.2016.02.009 Research Advances of Solid State Electrolyte with Cation Conduction 1 1 1,2 1 1,2 SHI Ming , ZHOU Hui-zhu , DAI Lei , LI Yue-hua , WANG Ling (1. College of Chemical Engineering, North China University of Science and Technology, Tangshan 063009, China; 2. Hebei Province Key Laboratory of Photocatalytic and Electrocatalytic Materials for Environment, Tangshan 063009, China) Abstract: Solid electrolytes have been widely studied as one of the functional materials in recent years. This paper mainly reviewed the newest research advances of cation conducting solid electrolytes with four valence states, especially those electrolytes conducting tri- and tetravalent ions. The application of the cation conductors in electrochemical gas sensors was also introduced briefly. At the same time, the facing challenges and the future prospect of solid electrolytes was discussed. Keywords: cation conducting solid electrolytes; NASICON; electrochemical gas sensors 1